HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diazomethane → Methyl 2-acetylnicotinate 4-phenylsemicarbazone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diazomethane | HCID 9550 | — |
| Reactant | HCID 178467405 | HCID 178467405 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | Methyl 2-acetylnicotinate 4-phenylsemicarbazone | HCID 67895943 | — |
Reaction Steps
A suspension of 2-acetylnicotinic acid 4-phenylsemicarbazone (compound 1) (0.50 g) in 20 ml of methanol is treated with diazomethane until the yellow color of the solution persists. The solvent is removed in vacuo to give methyl 2-acetylnicotinate 4-phenylsemicarbazone, m.p. 177°-178° (compound 53, Table C).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05098462 |
| Source dataset | uspto-grants-1992_03 |
| ORD ID | ord-fe3a37260c4b494e9b423c965baf167a |
| Source note | uspto-grants-1992_03 |