Acetone → HCID 19756610, compound

HRID 2372496Notes

Reaction equation

[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[CH2:11][O:12][C:13]1[CH:14]=[C:15](C(O)(CCC2(C)OCC(C)(C)CO2)CO)[CH:16]=[CH:17][CH:18]=1.[CH3:34][C:35]([CH3:37])=[O:36]>>[C:35]([CH2:37][CH2:34][C:35]1([C:15]2[CH:16]=[CH:17][CH:18]=[C:13]([O:12][CH2:11][C:2]3[CH:3]=[CH:4][C:5]4[C:10](=[CH:9][CH:8]=[CH:7][CH:6]=4)[CH:1]=3)[CH:14]=2)[CH2:37][O:12][C:13]([CH3:14])([CH3:18])[O:36]1)(=[O:36])[CH3:34]

Participants

Reactant 2

HCID 180Acetone

HCID 19756598HCID 19756598, compound

Product 1

HCID 19756610HCID 19756610, compoundYield 45%

Procedure

Using the procedure described in Example 1, 2-[3-(naphth-2-ylmethoxy)phenyl]-4-(2,5,5-trimethyl-1,3-dioxan-2-yl)butane-1,2-diol (0.77 g) was reacted with acetone to give 4-(2-acetylethyl)-2,2-dimethyl -4-[3-(naphth-2-ylmethoxy)phenyl]-1,3-dioxolane (0.32 g, 45%), as an oil.

Sources & evidence

ORD record: ord-edbaed8f334046dfafbe5baf91f5331a
Source dataset: uspto-grants-1992_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05098932

Reaction notes

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