Acetone → HCID 19756620, compound

HRID 2372498Notes

Reaction equation

[N+:1]([C:4]1[CH:5]=[C:6]([O:15][CH2:16][C:17]#[C:18][C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)[CH:7]=[C:8]([C:10]([OH:14])([CH3:13])[CH2:11][OH:12])[CH:9]=1)([O-:3])=[O:2].[CH3:25][C:26]([CH3:28])=O>>[CH3:25][C:26]1([CH3:28])[O:14][C:10]([CH3:13])([C:8]2[CH:9]=[C:4]([N+:1]([O-:3])=[O:2])[CH:5]=[C:6]([O:15][CH2:16][C:17]#[C:18][C:19]3[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=3)[CH:7]=2)[CH2:11][O:12]1

Participants

Reactant 2

HCID 180Acetone

HCID 19756585HCID 19756585, compound

Product 1

HCID 19756620HCID 19756620, compoundYield 95%

Procedure

Using the procedure described in Example 1, 2-[5-nitro-3-(3-phenylprop-2-ynyloxy)phenyl]propane-1,2-diol was reacted with acetone to give 2,2,4-trimethyl-4-[5-nitro-3-(3-phenylprop-2-ynyloxy)phenyl]-1,3-dioxolane in 95% yield, as an oil.

Sources & evidence

ORD record: ord-0c46ce77f9504567a394651912570531
Source dataset: uspto-grants-1992_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05098932

Reaction notes

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