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HRID2372981

反应详情

EQUATION

反应方程式

HRID 2372981 的结构方程式

REACTANTS

反应物

2
结构：C[O-].[Na+]
HCID10942334

Methanol, sodium salt

CH3NaO

结构：CC(=O)O[C@@H]1[C@@H](OC(C)=O)[C@H](Sc2ccc(-c3ccc(C#N)cc3)cc2)SC[C@H]1OC(C)=O
HCID14795359

未命名化合物

PRODUCTS

生成物

1
结构：N#Cc1ccc(-c2ccc(S[C@@H]3SC[C@@H](O)[C@H](O)[C@H]3O)cc2)cc1
HCID14795391

未命名化合物

收率 80%

PROCEDURE

实验过程

If the procedure described in Preparation V is followed starting from 0.340 g (70.1.10-3 mol) of 4-(4-cyanophenyl)phenyl 2,3,4-tri-O-acetyl-1,5-dithio-β-D-xylopyranoside (Example 14a) and 17 ml of sodium methylate (8% w/v solution of Na in methanol), 0.200 g (yield: 80%) of the expected product is obtained after purification by recrystallization from methanol.

WORKUP

后处理

  1. customIf the procedure described in Preparation V