5-Bromosalicylic acid → HCID 69207175, compound

HRID 2373807Notes

Reaction equation

HRID 2373807 reaction equation
Br[C:2]1[CH:10]=[C:6]([C:7]([OH:9])=[O:8])[C:5]([OH:11])=[CH:4][CH:3]=1.[N+:12]([C:15]1[CH:20]=[CH:19][C:18](B(O)O)=[CH:17][CH:16]=1)([O-:14])=[O:13]>>[OH:11][C:5]1[CH:4]=[CH:3][C:2]([C:18]2[CH:19]=[CH:20][C:15]([N+:12]([O-:14])=[O:13])=[CH:16][CH:17]=2)=[CH:10][C:6]=1[C:7]([OH:9])=[O:8]

Participants

3

Reactant 2

HCID 69725-Bromosalicylic acidHCID 27735524-Nitrophenylboronic acid

Product 1

HCID 69207175HCID 69207175, compound

Procedure

4-Hydroxy-4′-nitro-biphenyl-3-carboxylic acid (1.98) was prepared from 5-bromosalicylic acid (2.6 g, 11.9 mmol ) and 4-nitrophenylboronic acid (3.0 g, 17.9) following general procedure D

Sources & evidence

ORD record
ord-8844daf6c3af42768cadedf09a809400
Source dataset
uspto-grants-2008_12
Patent number
US07459472B2

Reaction notes

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