1,2-Dihydronaphthalene → 1,2-Epoxy-1,2,3,4-tetrahydronaphthalene

HRID 2375253Notes

Reaction equation

HRID 2375253 reaction equation
[CH2:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][CH2:2]1.[OH:11]OS([O-])=O.[K+]>>[O:11]1[CH:8]2[CH2:7][CH2:6][C:5]3[C:10]([CH:9]12)=[CH:1][CH:2]=[CH:3][CH:4]=3

Participants

3

Reactant 2

HCID 99381,2-DihydronaphthaleneHCID 23707502Potassium hydroxy sulfite

Product 1

HCID 921821,2-Epoxy-1,2,3,4-tetrahydronaphthalene

Procedure

36.5 g of 1,2-dihydronaphthalene (280.3 mmol) are treated with Oxone® according to the method described in Step A of Example 8 to yield the expected product in the form of an oil.

Sources & evidence

ORD record
ord-b27470c677054a40978d64824eedd937
Source dataset
uspto-grants-2008_12
Patent number
US07465733B2

Reaction notes

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