4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine → 4-(4-Bromo-3,5-dimethyl-phenyl)-pyridine

Participants

Role	Name	HCID	Charge
Reactant	4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine	HCID 2734648	—
Reactant	2-Bromo-5-iodo-1,3-dimethylbenzene	HCID 20748037	—
Product	4-(4-Bromo-3,5-dimethyl-phenyl)-pyridine	HCID 86697289	—

Reaction Steps

The title compound is prepared from 4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-pyridine and 2-bromo-5-iodo-1,3-dimethyl-benzene following a procedure analogous to that described in Step 1 of Intermediate 56. LC (method 9): tR=0.90 min; Mass spectrum (ESI+): m/z=262/264 (Br) [M+H]+.

Provenance & Evidence

DOI	10.6084/m9.figshare.5104873.v1
Patent number	US08642585B2
Source dataset	uspto-grants-2014_02
ORD ID	ord-f5aa3261535c4234bd6ca9af8d218120
Source note	uspto-grants-2014_02