5-Hexen-1-ol → N-{[(Hex-5-en-1-yl)oxy]carbonyl}-3-methyl-L-valine

HRID 2377609Notes

Reaction equation

HRID 2377609 reaction equation
[CH3:1][C:2]([CH3:17])([CH3:16])[C@@H:3]([C:13]([OH:15])=[O:14])[NH:4][C:5]([O:7][CH2:8][CH2:9][CH2:10][CH:11]=[CH2:12])=[O:6].[CH2:18](O)CCCC=C>>[CH3:1][C:2]([CH3:17])([CH3:16])[C@@H:3]([C:13]([OH:15])=[O:14])[NH:4][C:5]([O:7][CH2:8][CH2:9][CH2:10][CH2:11][CH:12]=[CH2:18])=[O:6]

Participants

3

Reactant 2

HCID 699635-Hexen-1-olHCID 453799283-Methyl-N-{[(pent-4-en-1-yl)oxy]carbonyl}-L-valine

Product 1

HCID 45378514N-{[(Hex-5-en-1-yl)oxy]carbonyl}-3-methyl-L-valine

Procedure

3-Methyl-N-[(hex-5-enyloxy)carbonyl]-L-valine was prepared according to the procedure for 3-methyl-N-[(pent-4-enyloxy)carbonyl]-L-valine by using 5-hexenol instead of 4-pentenol. LRMS (ESI) m/z 258 [(M+H)+; calcd for C13H24NO4: 258].

Sources & evidence

ORD record
ord-45433ee59a0b4b41bcfbad7dc1d79c4f
Source dataset
uspto-grants-2008_12
Patent number
US07470664B2

Reaction notes

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