HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-(Bromomethyl)-5-methyl-1,3-dioxol-2-one → HCID 14210554, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-(Bromomethyl)-5-methyl-1,3-dioxol-2-one | HCID 10774141 | — |
| Reactant | HCID 67828894 | HCID 67828894 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | HCID 14210554 | HCID 14210554 | — |
Reaction Steps
Analogously to Example 7, 6.3 g of pyridine-2,5-dicarboxylic acid sodium salt are reacted with 14.3 g of 5-methyl-2-oxo-1,3-dioxol-4-yl-methyl bromide and the mixture is boiled under reflux in acetone for 2.5 hours. After chromatography over silica gel with ethyl acetate as the mobile phase, the product is recrystallized from hot ethyl acetate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05364873 |
| Source dataset | uspto-grants-1994_11 |
| ORD ID | ord-5d437180dfb840a28182247572cbe605 |
| Source note | uspto-grants-1994_11 |