Diisopropylaniline → HCID 10615554, compound

Participants

Reaction Conditions

Reaction Steps

A solution of 2,6-diisopropylaniline (30.0 g, 0.169 moles) in 150 mL Et2O was added dropwise to a solution of N-chlorosulfonyl isocyanate (14.73 mL, 0.169 moles) in 100 mL Et2O at -15° C. (acetone/ice bath) under an atmosphere of N2. The resulting off-white suspension was stirred at -15° C. for 1 hour and the solid was collected by vacuum filtration. The solid was washed with hexanes and air dried to give 53.79 g (99%) of the title compound as a white solid, mp 130°-134° C.

Provenance & Evidence