Ethene--prop-1-ene (1/1) → HCID 86748291, compound

HRID 2380724Notes

Reaction equation

HRID 2380724 reaction equation
[I:1][CH2:2][CH2:3][CH:4]=[CH2:5].[Al](I)(CC)CC.C=C.[CH2:14]=[CH:15][CH3:16]>C1(C)C=CC=CC=1>[CH2:2]=[CH2:3].[CH2:14]=[CH:15][CH3:16].[I:1][CH2:2][CH2:3][CH:4]=[CH2:5]

Participants

5

Reactant 3

HCID 62702Ethene--prop-1-ene (1/1)HCID 74874Diethylaluminum iodideHCID 5432164-Iodobut-1-ene

Product 1

HCID 86748291HCID 86748291, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

Into a 2 liter glass autoclave heated at the desidered temperature, toluene, 1-iodo-3-butene, V(acetylacetonate)3 and AlEt2I were introduced under nitrogen flow. A continuous constant ratio ethylene/propylene flow was then introduced.

Workup

  1. additionwere introduced under nitrogen flow

Sources & evidence

ORD record
ord-173aa00af34e48d88f045ab52f42fcc0
Source dataset
uspto-grants-1994_11
Patent number
US05369186

Reaction notes

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