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2,6-Dimethylaniline → N-(2,6-Dimethylphenyl)formamide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2,6-Dimethylaniline | HCID 6896 | — |
| 反応物 | Sodium Acetate | HCID 517045 | — |
| 溶媒 | Formic Acid | HCID 284 | — |
| 生成物 | N-(2,6-Dimethylphenyl)formamide | HCID 345859 | 79% |
反応手順
4.1 10.0 g of sodium acetate are dissolved in 120 ml of formic acid. 50.0 g of 2,6-dimethylaniline 11 are then introduced, and the mixture is stirred under reflux for 24 h. The mixture is subsequently subjected to conventional work-up, giving 48.9 g (79%) of N-(2,6-dimethylphenyl)formamide 12; MS-EI (M+)=149.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08258151B2 |
| 出典データセット | uspto-grants-2012_09 |
| ORD ID | ord-ecafce52565e444bbd417d8c3ac09ba6 |
| 出典メモ | uspto-grants-2012_09 |