2,4,4-Trimethyl-1-pentene → HCID 178460681, compound

HRID 2381873Notes

Reaction equation

[CH3:1][C:2]([CH2:4][C:5]([CH3:8])([CH3:7])[CH3:6])=[CH2:3].C(OOC(=O)C1C=CC=CC=1)(C)(C)C.[PH2:23]([OH:25])=[O:24]>>[CH3:3][CH:2]([CH2:4][C:5]([CH3:8])([CH3:7])[CH3:6])[CH2:1][PH:23](=[O:24])[OH:25]

Participants

Reactant 3

HCID 78682,4,4-Trimethyl-1-pentene

HCID 11966tert-Butyl peroxybenzoate

HCID 4124402Phosphinic Acid

Product 1

HCID 178460681HCID 178460681, compound

Procedure

A mixture of diisobutylene (112 g, 1 mol) and hypophosphorous acid (30%, 230 mL) are reacted in the presence of t-butylperbenzoate. After aqueous work up, 45 g of oily product are obtained. It is characterized by 1H NMR and 31P NMR which shows formation of product (64% pure).

Sources & evidence

ORD record: ord-673dd48eb5b44b99803ec3606532f55e
Source dataset: uspto-grants-2012_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08258253B2

Reaction notes

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