Phenylhydrazine → N-Phenanthridin-6-yl-N'-phenylhydrazine hydrochloride

HRID 2382150Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2382150
[C:1]1([NH:7][NH2:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cl:9][C:10]1[N:11]=[C:12]2[C:17](=[C:18]3[C:23]=1[CH:22]=[CH:21][CH:20]=[CH:19]3)[CH:16]=[CH:15][CH:14]=[CH:13]2>C(O)C>[ClH:9].[CH:16]1[C:17]2[C:12](=[N:11][C:10]([NH:8][NH:7][C:1]3[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=3)=[C:23]3[C:18]=2[CH:19]=[CH:20][CH:21]=[CH:22]3)[CH:13]=[CH:14][CH:15]=1

Komponenten

4

Edukt 2

HCID 7516PhenylhydrazineHCID 2699686-Chlorophenanthridine

Produkt 1

HCID 67128370N-Phenanthridin-6-yl-N'-phenylhydrazine hydrochloride

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel

Versuchsvorschrift

Phenylhydrazine (1.3 g, 12 mmol) is dissolved in ethanol (50 ml) and admixed under argon with 6-chlorophenanthridine (A. G. Mikhailovskii, V. S. Shklyaev, Chem. Heterocycl. Comp. 1992, 445) (2.1 g, 10 mmol). The mixture is stirred under reflux for 16 h. After cooling to room temperature, the mixture is concentrated and the resulting precipitate is filtered off and washed with methyl tert-butyl ether. Yield: 2.6 g (82%).

Aufarbeitung

  1. temperatureunder reflux for 16 h
  2. concentrationthe mixture is concentrated
  3. filtrationthe resulting precipitate is filtered off
  4. washwashed with methyl tert-butyl ether

Quellen und Nachweise

ORD-Eintrag
ord-da976a914be04d299ea100de1b05a0e1
Quelldatensatz
uspto-grants-2012_09
Patentnummer
US08258297B2

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