Sulfuric Acid → HCID 57740578, compound

Participants

Reaction Conditions

Reaction Steps

Ethylene (15 g) was introduced to an autoclave charged with C6F13CH2CF2I (170 g) and d-(+)-limonene (1 g), and then the reactor was heated at 240° C. for 12 h. Product was isolated by vacuum distillation to provide C6F13CH2CF2CH2CH2I. Fuming sulfuric acid (129 mL) was added slowly to C6F13CH2CF2CH2CH2I (112 g). The mixture was stirred at 60° C. for 1.5 h. Then the reaction was quenched with ice-cold 1.5 wt % aqueous Na2SO3 and heated at 95° C. for 0.5 h. The bottom layer was separated and washed with 10% sodium acetate aqueous solution and distilled to provide C6F13CH2CF2CH2CH2OH.: mp 38° C.

Provenance & Evidence