Benzenamine, 3,5-bis(trifluoromethyl)- → HCID 135544336, compound

HRID 2384388Notes

Reaction equation

HRID 2384388 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([N:10]=[N:11][C:12]2[CH:20]=[C:16]([C:17]([OH:19])=O)[C:15]([OH:21])=[CH:14][CH:13]=2)=[CH:6][CH:5]=1)([O-:3])=[O:2].[F:22][C:23]([F:36])([F:35])[C:24]1[CH:25]=[C:26]([CH:28]=[C:29]([C:31]([F:34])([F:33])[F:32])[CH:30]=1)[NH2:27]>>[F:22][C:23]([F:35])([F:36])[C:24]1[CH:25]=[C:26]([NH:27][C:17](=[O:19])[C:16]2[CH:20]=[C:12]([N:11]=[N:10][C:7]3[CH:6]=[CH:5][C:4]([N+:1]([O-:3])=[O:2])=[CH:9][CH:8]=3)[CH:13]=[CH:14][C:15]=2[OH:21])[CH:28]=[C:29]([C:31]([F:32])([F:34])[F:33])[CH:30]=1

Participants

3

Reactant 2

HCID 9480Benzenamine, 3,5-bis(trifluoromethyl)-HCID 15588Alizarin Yellow R

Product 1

HCID 135544336HCID 135544336, compoundYield 11.3%

Procedure

Using 5-[(4-nitrophenyl)diazenyl]salicylic acid and 3,5-bis(trifluoromethyl)aniline as the raw materials, the same operation as the example 16 gave the title compound.

Sources & evidence

ORD record
ord-495891cccde04126ae1ed8f0e8d241ad
Source dataset
uspto-grants-2012_09
Patent number
US08263657B2

Reaction notes

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