HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Fluoropyridine-3-boronic acid → HCID 58203787, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Fluoropyridine-3-boronic acid | HCID 2783270 | — |
| Reactant | HCID 67050574 | HCID 67050574 | — |
| Product | HCID 58203787 | HCID 58203787 | 61% |
Reaction Steps
Methyl 9-bromo-6,7-dihydrothieno[2,3-d]pyrido[3,2-b]oxepine-3-carboxylate was coupled with 2-fluoropyridin-3-ylboronic acid under Suzuki conditions to give methyl 9-(2-fluoropyridin-3-yl)-6,7-dihydrothieno[2,3-d]pyrido[3,2-b]oxepine-3-carboxylate. Yield 61%. MS (ESI+): 357.1
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08263633B2 |
| Source dataset | uspto-grants-2012_09 |
| ORD ID | ord-5f96eb3ad45b40b2a75dfa6b398d880b |
| Source note | uspto-grants-2012_09 |