Silver Nitrate → HCID 178442997, compound

HRID 2386104Notes

Reaction equation

HRID 2386104 reaction equation
[CH2:1]([CH:3]([CH2:25][CH2:26][CH2:27][CH3:28])[CH2:4][C:5]([CH2:17][CH:18]([CH2:23][CH3:24])[CH2:19][CH2:20][CH2:21][CH3:22])([C:14]([O-:16])=[O:15])[CH:6]([S:10]([OH:13])(=[O:12])=[O:11])[C:7]([O-:9])=[O:8])[CH3:2].[Na+].[Na+].[N+]([O-])([O-])=O.[Ag+:35]>C(OCC)C>[CH2:1]([CH:3]([CH2:25][CH2:26][CH2:27][CH3:28])[CH2:4][C:5]([CH2:17][CH:18]([CH2:23][CH3:24])[CH2:19][CH2:20][CH2:21][CH3:22])([C:14]([O-:16])=[O:15])[CH:6]([S:10]([OH:13])(=[O:11])=[O:12])[C:7]([O-:9])=[O:8])[CH3:2].[Ag+2:35]

Participants

4

Reactant 2

HCID 24470Silver NitrateHCID 22323434HCID 22323434, compound

Product 1

HCID 178442997HCID 178442997, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

Sodium bis(2-ethylhexyl)sulfosuccinate (NaAOT) is obtained from Fisher. 10 g NaAOT is dissolved in 100 mL diethylether and combined with an equal volume of 0.1 M aqueous AgNO3 in a separatory flask. The mixture is shaken and the aqueous phase was decanted. Two additional 100 mL volumes of 0.1 M AgNO3 are similarly ion exchanged with the ether solution. The ether solution is then washed twice with deionized water. The aqueous phase is decanted and the ether phase is reduced to a paste using rotary evaporation. The remaining paste is dried in a vacuum oven at 25-50° C., and a yield in excess of 90% is obtained.

Workup

  1. customthe aqueous phase was decanted
  2. washThe ether solution is then washed twice with deionized water
  3. customThe aqueous phase is decanted
  4. customevaporation
  5. customThe remaining paste is dried in a vacuum oven at 25-50° C.
  6. customa yield in excess of 90%
  7. customis obtained

Sources & evidence

ORD record
ord-aaa1858435ca4d789edd9ca9f8635676
Source dataset
uspto-grants-2012_09
Patent number
US08268338B2

Reaction notes

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