3-(Tributylstannyl)pyridine → HCID 136401500, compound

HRID 2388162Notes

Reaction equation

HRID 2388162 reaction equation
[CH2:1]([O:3][C:4]([C:6]1[C:7]([OH:22])=[C:8]2[C:15]([C:16]3[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=3)=[N:14][O:13][C:9]2=[C:10](Br)[N:11]=1)=[O:5])[CH3:2].CCCC[Sn]([C:36]1[CH:41]=[CH:40][CH:39]=[N:38][CH:37]=1)(CCCC)CCCC>>[CH2:1]([O:3][C:4]([C:6]1[C:7]([OH:22])=[C:8]2[C:15]([C:16]3[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=3)=[N:14][O:13][C:9]2=[C:10]([C:36]2[CH:37]=[N:38][CH:39]=[CH:40][CH:41]=2)[N:11]=1)=[O:5])[CH3:2]

Participants

3

Reactant 2

HCID 34838483-(Tributylstannyl)pyridineHCID 136399879HCID 136399879, compound

Product 1

HCID 136401500HCID 136401500, compound

Procedure

Prepared in analogy to Example 12 from 7-Bromo-4-hydroxy-3-phenyl-isoxazolo[5,4-c]pyridine-5-carboxylic acid ethyl ester and 3-(1,1,1-tributylstannyl)pyridine; ESI MS (m/z): 362.23 (M+H+); 360.13 (M−H+).

Sources & evidence

ORD record
ord-99fe12b9b74541beb35bcf30df33b047
Source dataset
uspto-grants-2012_09
Patent number
US08269008B2

Reaction notes

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