HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,1'-Carbonyldiimidazole → HCID 135894684, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,1'-Carbonyldiimidazole | HCID 68263 | — |
| Reactant | 1,8-Diazabicyclo(5.4.0)undec-7-ene | HCID 81184 | — |
| Reactant | HCID 178513337 | HCID 178513337 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | HCID 135894684 | HCID 135894684 | — |
Reaction Steps
A mixture of the above intermediate from Step B (0.044 g, 0.1 mmol), 1,1′-carbonyldiimidazole (Aldrich, 0.0178 g, 0.11 mmol), DBU (Acros, 0.06 mL, 0.4 mmol) in CH3CN (1 mL) was stirred at rt overnight. The crude product was purified by HPLC to give a TFA salt as a yellowish solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08269015B2 |
| Source dataset | uspto-grants-2012_09 |
| ORD ID | ord-6918e329978249e1ba6ade94d968e14e |
| Source note | uspto-grants-2012_09 |