Decanoic Acid → HCID 11855340, compound

HRID 238902Notes

Reaction equation

HRID 238902 reaction equation
[CH2:1]([CH:4]([CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:5][OH:6])[CH2:2][CH3:3].[OH:12][C:13]([CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23])=O>O>[O:6]([CH2:5][CH:4]([CH2:1][CH2:2][CH3:3])[CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[C:13]([CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23])=[O:12]

Participants

4

Reactant 2

HCID 2969Decanoic AcidHCID 248472-Propyl-1-heptanol

Product 1

HCID 11855340HCID 11855340, compoundYield 84.1%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

1108.0 g 2-propylheptanol (7 mol) and 1205.9 g capric acid (7 mol) were heated for 6 h to 220° C. on a water separator together with 0.27 g Fascat® 2001 (Sn oxalate: 0.1% by weight, based on the composition as a whole). After the separation of water had stopped, the crude product was distilled in an oil pump vacuum through a 250 mm Vigreux column (T=141-152° C.). 1840.1 g of a colorless oil were obtained: OHV=<0.08, AV=<0.18.

Workup

  1. customAfter the separation of water
  2. distillationthe crude product was distilled in an oil pump vacuum through a 250 mm Vigreux column (T=141-152° C.)

Sources & evidence

ORD record
ord-3ce96dc3c3ea4415ac0032bb67225897
Source dataset
uspto-grants-2014_02
Patent number
US08642652B2

Reaction notes

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