Phenol, 4-(pentyloxy)- → 2,2-Dimethyl-5-nitro-5-(6-(4-(pentyloxy)phenoxy)naphthalen-2-yl)-1,3-dioxane

HRID 2389170Notes

Reaction equation

HRID 2389170 reaction equation
[CH3:1][C:2]1([CH3:35])[O:7][CH2:6][C:5]([N+:32]([O-:34])=[O:33])([C:8]2[CH:17]=[CH:16][C:15]3[C:10](=[CH:11][CH:12]=[C:13]([O:18][C:19]4[CH:24]=[CH:23][C:22]([O:25][C:26]5C=[CH:30][CH:29]=[CH:28][CH:27]=5)=[CH:21][CH:20]=4)[CH:14]=3)[CH:9]=2)[CH2:4][O:3]1.C(OC1C=CC(O)=CC=1)CCCC>>[CH3:35][C:2]1([CH3:1])[O:3][CH2:4][C:5]([N+:32]([O-:34])=[O:33])([C:8]2[CH:17]=[CH:16][C:15]3[C:10](=[CH:11][CH:12]=[C:13]([O:18][C:19]4[CH:20]=[CH:21][C:22]([O:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])=[CH:23][CH:24]=4)[CH:14]=3)[CH:9]=2)[CH2:6][O:7]1

Participants

3

Reactant 2

HCID 29353Phenol, 4-(pentyloxy)-HCID 866429072,2-Dimethyl-5-nitro-5-(6-(4-phenoxyphenoxy)naphthalen-2-yl)-1,3-dioxane

Product 1

HCID 866429092,2-Dimethyl-5-nitro-5-(6-(4-(pentyloxy)phenoxy)naphthalen-2-yl)-1,3-dioxaneYield 58%

Procedure

2,2-dimethyl-5-nitro-5-(6-(4-(pentyloxy)phenoxy)naphthalen-2-yl)-1,3-dioxane was synthesized as per 2,2-dimethyl-5-nitro-5-(6-(4-phenoxyphenoxy)naphthalen-2-yl)-1,3-dioxane (Example 243) in 58% yield using 4-pentyloxy-phenol as the reagent.

Sources & evidence

ORD record
ord-b1ee1f3fdf2f4f33b84b84297fc5b535
Source dataset
uspto-grants-2012_09
Patent number
US08269043B2

Reaction notes

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