Ammonia → HCID 178429033, compound

HRID 2389613Notes

Reaction equation

HRID 2389613 reaction equation
[CH3:1][C:2]1OC(=O)[CH:6]([C:10]([CH3:12])=O)[C:4](=[O:5])[CH:3]=1.[NH3:13]>>[CH3:1][C:2]1[CH:3]=[C:4]([OH:5])[CH:6]=[C:10]([CH3:12])[N:13]=1

Participants

3

Reactant 2

HCID 222AmmoniaHCID 122903Dehydroacetic acid

Product 1

HCID 178429033HCID 178429033, compound

Procedure

Five separate batches of dehydroacetic acid (1.5 g, 8.92 mmol) are each suspended in conc. ammonia (4 mL) and irradiated at 120° C. for 20 minutes (150 W, Discover® System microwave reactor by CEM Corporation, Matthews, N.C., USA) in the microwave. Once cooled, the solutions are combined and evaporated to dryness to afford the title compound.

Workup

  1. customirradiated at 120° C. for 20 minutes (150 W, Discover® System microwave reactor by CEM Corporation, Matthews, N.C., USA) in the microwave
  2. temperatureOnce cooled
  3. customevaporated to dryness

Sources & evidence

ORD record
ord-57340e17aa984b89ac5c96a98ede886d
Source dataset
uspto-grants-2012_09
Patent number
US08273747B2

Reaction notes

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