Tetraethoxysilane → HCID 131720807, compound

HRID 2392507Notes

Reaction equation

HRID 2392507 reaction equation
[CH3:1][CH2:2][CH2:3][CH2:4][CH:5]([CH2:8][CH2:9][CH:10]([O:15][S:16]([O-:19])(=[O:18])=[O:17])[CH2:11][CH:12]([CH3:14])[CH3:13])[CH2:6][CH3:7].[Na+:20].[Si:21]([O:31][CH2:32][CH3:33])([O:28][CH2:29][CH3:30])([O:25][CH2:26][CH3:27])[O:22][CH2:23][CH3:24]>O>[Si:21]([O:25][CH2:26][CH3:27])([O:28][CH2:29][CH3:30])([O:31][CH2:32][CH3:33])[O:22][CH2:23][CH3:24].[CH3:1][CH2:2][CH2:3][CH2:4][CH:5]([CH2:8][CH2:9][CH:10]([O:15][S:16]([O-:19])(=[O:18])=[O:17])[CH2:11][CH:12]([CH3:13])[CH3:14])[CH2:6][CH3:7].[Na+:20]

Participants

4

Reactant 2

HCID 6517TetraethoxysilaneHCID 23665772Sodium Tetradecyl Sulfate

Product 1

HCID 131720807HCID 131720807, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A 0.02M solution of an alkyl polyethylene oxide C11-15H23-31 --(CH2CH2O)15H (TERGITOL 15-S-15, Union Carbide, Danbury, Conn.) was prepared by dissolution of 0.877 g of TERGITOL in 50 mL of water. After complete dissolution, 1.664 g of tetraethyl orthosilicate (TEOS) was then added at room temperature in order to obtain a molar ratio TEOS/TERGITOL 15-S-15=8, while the solution was sonicated. The so obtained solution was cloudy. The sonication was stopped and the solution was allowed to stand for around 12 hours, until it had formed a clear colorless solution.

Workup

  1. additionwas then added at room temperature in order

Sources & evidence

ORD record
ord-34d670159b5c40c49da9a31c08de014a
Source dataset
uspto-grants-1998_09
Patent number
US05800799

Reaction notes

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