HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 22091595, compound → HCID 86753060, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 22091595 | HCID 22091595 | — |
| Catalyst | Manganese dioxide | HCID 14801 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 86753060 | HCID 86753060 | 84.3% |
Reaction Steps
3.42 g (E)-3-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-naphthalen-2-yl)-but-2-en-1-ol were dissolved in 23 ml of CH2Cl2 and treated with 16.1 g of MnO2. The reaction mixture was vigorously stirred at ambient temperature over night and then filtered through Celite. Evaporation of the solvent followed by flash chromatography (silica gel, hexane/AcOEt=92:8) afforded 2.86 g of (E)-3-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-naphthalen-2-yl)-but-2-enal as pale yellow oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05801253 |
| Source dataset | uspto-grants-1998_09 |
| ORD ID | ord-fa1d6937761c4971953b3d2f97c66048 |
| Source note | uspto-grants-1998_09 |