Dimesitylboron fluoride → HCID 11343389, compound

HRID 2393679Notes

Reaction equation

[C:1]1([CH3:48])[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[B:9]([C:39]1[C:44]([CH3:45])=[CH:43][C:42]([CH3:46])=[CH:41][C:40]=1[CH3:47])[C:10]1[CH:11]=[C:12]([Si](C)(C)C)[CH:13]=[C:14]([B:16]([C:26]2[C:31]([CH3:32])=[CH:30][C:29]([CH3:33])=[CH:28][C:27]=2[CH3:34])[C:17]2[C:22]([CH3:23])=[CH:21][C:20]([CH3:24])=[CH:19][C:18]=2[CH3:25])[CH:15]=1.[C:49]1([CH3:68])[CH:54]=[C:53]([CH3:55])[CH:52]=[C:51]([CH3:56])[C:50]=1[B:57]([C:59]1[C:64]([CH3:65])=[CH:63][C:62]([CH3:66])=[CH:61][C:60]=1[CH3:67])F>>[C:1]1([CH3:48])[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[B:9]([C:39]1[C:44]([CH3:45])=[CH:43][C:42]([CH3:46])=[CH:41][C:40]=1[CH3:47])[C:10]1[CH:11]=[C:12]([B:57]([C:59]2[C:60]([CH3:67])=[CH:61][C:62]([CH3:66])=[CH:63][C:64]=2[CH3:65])[C:50]2[C:51]([CH3:56])=[CH:52][C:53]([CH3:55])=[CH:54][C:49]=2[CH3:68])[CH:13]=[C:14]([B:16]([C:26]2[C:31]([CH3:32])=[CH:30][C:29]([CH3:33])=[CH:28][C:27]=2[CH3:34])[C:17]2[C:22]([CH3:23])=[CH:21][C:20]([CH3:24])=[CH:19][C:18]=2[CH3:25])[CH:15]=1

Participants

Reactant 2

HCID 3466040Dimesitylboron fluoride

HCID 18787958HCID 18787958, compound

Product 1

HCID 11343389HCID 11343389, compoundYield 73%

Procedure

The compound of Example 40 is prepared similarly to the compound from Example 29 by threefold treatment with dimesitylfluoroborane. The yield is 73%. Physical data are given in Table 1.

Sources & evidence

ORD record: ord-e69af017bebc44eb83fa47b648b0d52d
Source dataset: uspto-grants-1998_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05807905

Reaction notes

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