Benzene, [1-[(trimethylsilyl)oxy]ethenyl]- → HCID 54681266, compound

HRID 2394045Notes

Reaction equation

HRID 2394045 reaction equation
[C:1]1([C:7]([O:9][Si](C)(C)C)=[CH2:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:14]([C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=1[S:23][CH:24]([C:28](O)=[O:29])[C:25](O)=[O:26])[CH2:15][CH3:16]>>[OH:29][C:28]1[CH:8]=[C:7]([C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)[O:9][C:25](=[O:26])[C:24]=1[S:23][C:18]1[CH:19]=[CH:20][CH:21]=[CH:22][C:17]=1[CH2:14][CH2:15][CH3:16]

Participants

3

Reactant 2

HCID 117406Benzene, [1-[(trimethylsilyl)oxy]ethenyl]-HCID 19596215HCID 19596215, compound

Product 1

HCID 54681266HCID 54681266, compound

Procedure

The title compound was prepared by Method A using 1-phenyl-1-(trimethylsilyloxy)ethylene (0.990 mL, 4.83 mmol) and diethyl ester of [(2-propylphenyl)thio]propanedioic acid (1.00 g, 3.22 mmol). m.p. 158°-160° C.; 1H NMR (400 MHz, DMSO-d6) δ 0.972 (t, 3H), 1.64 (m, 2H), 2.71 (t, 2H), 6.87 (s, 1H), 6.92 (m, 1H), 7.06 (m, 2H), 7.16 (m, 1H), 7.55 (m, 3H), 7.85 (m, 2H).

Sources & evidence

ORD record
ord-051c923d0a6b458bb923e96d4e94b3c3
Source dataset
uspto-grants-1998_09
Patent number
US05808062

Reaction notes

Loading…