Benzene, [1-[(trimethylsilyl)oxy]ethenyl]- → HCID 54681231, compound

HRID 2394058Notes

Reaction equation

HRID 2394058 reaction equation
[C:1]1([C:7]([O:9][Si](C)(C)C)=[CH2:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:14]1([S:24][CH:25]([C:29](O)=[O:30])[C:26](O)=[O:27])[C:23]2[C:18](=[CH:19][CH:20]=[CH:21][CH:22]=2)[CH:17]=[CH:16][CH:15]=1>>[OH:30][C:29]1[CH:8]=[C:7]([C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)[O:9][C:26](=[O:27])[C:25]=1[S:24][C:14]1[C:23]2[C:18](=[CH:19][CH:20]=[CH:21][CH:22]=2)[CH:17]=[CH:16][CH:15]=1

Participants

3

Reactant 2

HCID 117406Benzene, [1-[(trimethylsilyl)oxy]ethenyl]-HCID 19596237HCID 19596237, compound

Product 1

HCID 54681231HCID 54681231, compound

Procedure

The title compound was prepared by Method A using 1-phenyl-1-(trimethylsilyloxy)ethylene (1.95 g, 10.14 mmol) and diethyl ester of [(1-naphthyl)thio]propanedioic acid (1.61 g, 5.07 mmol). m.p. 242°-243° C.; 1H NMR (400 MHz, DMSO-d6) δ 6.83 (s, 1H), 7.19 (d, 1H)., 7.39 (t, 1H), 7.64-7.42 (m, 5H), 7.69 (d, 1H), 7.83 (m, 2H), 7.94 (d, 1H), 8.28 (d, 1H).

Sources & evidence

ORD record
ord-06aa374a98344b39a41a2018dc6ddef4
Source dataset
uspto-grants-1998_09
Patent number
US05808062

Reaction notes

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