Ethylene → HCID 54681358, compound

HRID 2394064Notes

Reaction equation

HRID 2394064 reaction equation
[CH2:1]=[CH2:2].[CH:3]([C:6]1[CH:19]=[CH:18][CH:17]=[CH:16][C:7]=1[O:8][CH:9]([C:13]([OH:15])=O)[C:10]([OH:12])=[O:11])([CH3:5])[CH3:4]>>[OH:15][C:13]1[CH:2]=[C:1]([C:6]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:7]=2)[O:12][C:10](=[O:11])[C:9]=1[O:8][C:7]1[CH:16]=[CH:17][CH:18]=[CH:19][C:6]=1[CH:3]([CH3:4])[CH3:5]

Participants

3

Reactant 2

HCID 6325EthyleneHCID 19596063HCID 19596063, compound

Product 1

HCID 54681358HCID 54681358, compound

Procedure

The title compound was prepared by Method A using 1-phenyl-1-trimethylsilyloxy)ethylene (2.62 g, 13.6 mmol) and diethyl ester of 2-(isopropyl)phenoxy propanedioic acid (2.0 g, 6.8 mmol). 1 H NMR (250 MHz, DMSO-d6) δ 1.25 (d, 6H), 3.44 (m, 1H), 6.67 (d, 1H), 6.89 (s, 1H), 7.0 (t, 1H), 7.09 (t, 1H), 7.29 (d, 1H), 7.53 (m, 3H), 7.83 (m, 2H).

Sources & evidence

ORD record
ord-98c8d7838d3a44d692a8fa4207dcbd2e
Source dataset
uspto-grants-1998_09
Patent number
US05808062

Reaction notes

Loading…