Benzene, [1-[(trimethylsilyl)oxy]ethenyl]- → HCID 54681377, compound

HRID 2394077Notes

Reaction equation

HRID 2394077 reaction equation
[C:1]1([C:7]([O:9][Si](C)(C)C)=[CH2:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[F:14][C:15]([F:31])([F:30])[C:16]1[CH:17]=[C:18]([S:22][CH:23]([C:27](O)=[O:28])[C:24](O)=[O:25])[CH:19]=[CH:20][CH:21]=1>>[OH:28][C:27]1[CH:8]=[C:7]([C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)[O:9][C:24](=[O:25])[C:23]=1[S:22][C:18]1[CH:19]=[CH:20][CH:21]=[C:16]([C:15]([F:31])([F:14])[F:30])[CH:17]=1

Participants

3

Reactant 2

HCID 117406Benzene, [1-[(trimethylsilyl)oxy]ethenyl]-HCID 19596077HCID 19596077, compound

Product 1

HCID 54681377HCID 54681377, compound

Procedure

The title compound was prepared by Method A using 1-phenyl-1-(trimethylsilyloxy)ethylene (1.72 g, 8.92 mmol) and diethyl ester of [[3-(trifluoromethyl)phenyl]thio]propanedioic acid (1.5 g, 4.46 mmol). m.p. 228°-229° C.; 1H NMR (400 MHz, DMSO-d6) δ 6.89 (s, 1H), 7.4-7.61 (m, 7H), 7.89 (m, 2H).

Sources & evidence

ORD record
ord-66eded8a3ace4272a7001de3a961f49f
Source dataset
uspto-grants-1998_09
Patent number
US05808062

Reaction notes

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