1-Iodopyrene → HCID 19048327, compound

HRID 2395535Notes

Reaction equation

[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([N:8]([C:36]2[CH:41]=[CH:40][C:39]([CH3:42])=[CH:38][CH:37]=2)[C:9]2[C:14]([CH3:15])=[CH:13][C:12]([C:16]3[CH:32]=[C:31]([CH3:33])[C:19]([N:20]([C:24]4[CH:29]=[CH:28][C:27]([CH3:30])=[CH:26][CH:25]=4)[C:21](=O)[CH3:22])=[C:18]([CH3:34])[CH:17]=3)=[CH:11][C:10]=2[CH3:35])=[CH:4][CH:3]=1.I[C:44]1[C:57]2[C:58]3=[C:59]4[C:54](=[CH:55][CH:56]=2)C=C[CH:51]=[C:50]4[CH:49]=[CH:48][C:47]3=[CH:46][CH:45]=1>>[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([N:8]([C:36]2[CH:41]=[CH:40][C:39]([CH3:42])=[CH:38][CH:37]=2)[C:9]2[C:14]([CH3:15])=[CH:13][C:12]([C:16]3[CH:32]=[C:31]([CH3:33])[C:19]([N:20]([C:24]4[CH:29]=[CH:28][C:27]([CH3:30])=[CH:26][CH:25]=4)[C:21]4[C:54]5[C:59]6=[C:58]7[C:57](=[CH:56][CH:55]=5)[CH:44]=[CH:45][CH:46]=[C:47]7[CH:48]=[CH:49][C:50]6=[CH:51][CH:22]=4)=[C:18]([CH3:34])[CH:17]=3)=[CH:11][C:10]=2[CH3:35])=[CH:4][CH:3]=1

Participants

Reactant 2

HCID 135557141-Iodopyrene

HCID 19048326HCID 19048326, compound

Product 1

HCID 19048327HCID 19048327, compound

Procedure

The thus obtained N,N,N'-tris(4-methylphenyl)-N'-acetyl-3,3',5,5'-tetramethylbenzidine was hydrolyzed, and the hydrolyzed product and 1-iodo-pyrene were subjected to the same Ullmann reaction as in Preparation Example 1-6, whereby N,N,N'-tris(4-methylphenyl)-N'-(1-pyrenyl)-3,3',5,5'-tetramethylbenzidine (m.p. 198.0°-199.0° C.) was obtained.

Sources & evidence

ORD record: ord-8fa3d479e5cd439582681c4a65b83f8f
Source dataset: uspto-grants-1996_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05489495

Reaction notes

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