HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → HCID 18990344, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | Piperidine | HCID 8082 | — |
| Reactant | Acetylacetone | HCID 31261 | — |
| Reactant | 3-Chloro-4,5-dihydroxybenzaldehyde | HCID 2468182 | — |
| Solvent | Butyl Acetate | HCID 31272 | — |
| Product | HCID 18990344 | HCID 18990344 | — |
Reaction Steps
A mixture containing 3.45 g of 3,4-dihydroxy-5-chlorobenzaidehyde, 3.0 ml of 2,4-pentanedione, 0.3 ml of piperidine and 1.0 ml of acetic acid in 100 ml of 1-butyl acetate was refluxed for 2 h with Dean-Stark separator. The solution was filtered and the solvent was evaporated in vacuo. The residue was crystallized from 1-propanol. Yield 0.46 g, mp 167°-171° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05489614 |
| Source dataset | uspto-grants-1996_02 |
| ORD ID | ord-cb18d11043bd44bea42475d80da801bd |
| Source note | uspto-grants-1996_02 |