Potassium thiocyanate → Ethyl 2,2-dimethyl-6-thiocyanohexanate

HRID 2395952Notes

Reaction equation

Br[CH2:2][CH2:3][CH2:4][CH2:5][C:6]([CH3:13])([CH3:12])[C:7]([O:9][CH2:10][CH3:11])=[O:8].[S-:14][C:15]#[N:16].[K+]>>[CH3:12][C:6]([CH3:13])([CH2:5][CH2:4][CH2:3][CH2:2][S:14][C:15]#[N:16])[C:7]([O:9][CH2:10][CH3:11])=[O:8]

Participants

Reactant 2

HCID 516872Potassium thiocyanate

HCID 10444833Ethyl 6-bromo-2,2-dimethylhexanoate

Product 1

HCID 10489600Ethyl 2,2-dimethyl-6-thiocyanohexanate

Procedure

Using ethyl 6-bromo-2,2-dimethylhexanate as obtained in Reference Example 7and potassium thiocyanate, the title compound was produced in the same manner as in Reference Example 11.

Sources & evidence

ORD record: ord-4d0dad46f9aa4c5ba2d331e7fe6a3bec
Source dataset: uspto-grants-1996_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05491145

Reaction notes

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