HuagongsheHuagongshe Chemistry Print Report · For research reference only
(+-)-2-Butanol → (1-Methylpropoxycarbonyl)sulfenyl chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (+-)-2-Butanol | HCID 6568 | — |
| Reactant | (Chlorothio)formyl chloride | HCID 75990 | — |
| Product | (1-Methylpropoxycarbonyl)sulfenyl chloride | HCID 13633290 | 39.1% |
Reaction Steps
Chlorocarbonylsulfenyl chloride (13.1 g, 0.1 mol) was mixed with 2-butanol (6.7 g, 0.09 mol) and warmed to about 35° to 40° C. for one hour. Distillation resulted in the title compound (5.93 g) Bp. 70° C./0.8 mm Hg. NMR spectrum was consistent with the structure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05491162 |
| Source dataset | uspto-grants-1996_02 |
| ORD ID | ord-f3a4541cf8c5494da38a23b10ef300c7 |
| Source note | uspto-grants-1996_02 |