Dodecanoyl chloride → Sulfamic acid(dodecanoyl)-2,6-bis(1-methylethyl)phenyl ester

HRID 2396265Notes

Reaction equation

[CH3:1][CH:2]([C:4]1C=CC=C(C(C)C)[C:5]=1[CH2:13][C:14]([C:16]1[C:17]([CH:30]([CH3:32])[CH3:31])=[C:18]([O:25][S:26](=[O:29])(=[O:28])[NH2:27])[C:19]([CH:22]([CH3:24])[CH3:23])=[CH:20][CH:21]=1)=[O:15])C.[CH:33]([C:36]1C=C[CH:39]=[C:38](C(C)C)[C:37]=1CC(Cl)=O)(C)[CH3:34].C(Cl)(=O)CCCCCCCCCCC>>[C:14]([C:16]1[C:17]([CH:30]([CH3:32])[CH3:31])=[C:18]([O:25][S:26](=[O:28])(=[O:29])[NH2:27])[C:19]([CH:22]([CH3:24])[CH3:23])=[CH:20][CH:21]=1)(=[O:15])[CH2:13][CH2:5][CH2:4][CH2:2][CH2:1][CH2:34][CH2:33][CH2:36][CH2:37][CH2:38][CH3:39]

Participants

Reactant 3

HCID 8166Dodecanoyl chloride

HCID 10226443Sulfamic acid[[2,6-bis(1-methylethyl)phenyl]-acetyl]-2,6-bis(1-methylethyl)phenyl ester

HCID 193627822,6-Diisopropylphenylacetyl chloride

Product 1

HCID 10138111Sulfamic acid(dodecanoyl)-2,6-bis(1-methylethyl)phenyl ester

Procedure

This compound was prepared in the same manner as for the title compound of Example 1, except that 2,6-diisopropylphenylacetyl chloride was replaced with dodecanoyl chloride; 1H NMR (DMSO-26): δ 7.09 (s, 3H), 3.65 (heptet, 2H), 2.05 (t, 2H), 1.48-1.15 (m, 18H); 1.10 (d, 6H), 0.86 (t, 3H) ppm.

Sources & evidence

ORD record: ord-9c213fc0a3ee4fc099f0aba89b5157c5
Source dataset: uspto-grants-1996_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05491172

Reaction notes

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