Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
3-Bromo-1-propanol → 3-[(4,6-Diphenyl-2-pyridyl)oxy]-1-propanol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 3-Bromo-1-propanol | HCID 12308 | — |
| 반응물 | 4,6-Diphenyl-2-pyridone | HCID 3846201 | — |
| 촉매 | HCID 178418647 | HCID 178418647 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | 3-[(4,6-Diphenyl-2-pyridyl)oxy]-1-propanol | HCID 18987283 | — |
반응 단계
The procedure in Example 4 is followed but using 4,6-diphenyl-2-pyridone (15 g), freshly distilled 3-bromo-1-propanol (16.5 cc), silver carbonate (8.4 g) and toluene (600 cc). The reaction mixture is refluxed for 144 hours. The product is purified by chromatography under pressure on silica gel (30-60 mm; eluent: n-hexane-ethyl acetate 7-3). (white solid; m.p.=94° C.)
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05492915 |
| 출처 데이터셋 | uspto-grants-1996_02 |
| ORD ID | ord-3ba0fce85e394da99a4bd7067d820af7 |
| 출처 메모 | uspto-grants-1996_02 |