Chlorine → HCID 21436930, compound

Participants

Reaction Steps

44.3 g (0.2 mole) of 1,1-dimethyl-3-phospholenium chloride were suspended in 250 ml of chloroform and reacted with 14.2 g (0.2 mole) of chlorine at 20° C. After completion of the reaction, the reaction mixture was concentrated under reduced pressure. This gave 3,4-dichloro-1,1-dimethyl-phospholanium chloride in the form of colourless crystals of melting point 90°-100° C. (decomp.).

Provenance & Evidence