Diallylamine → HCID 20324729, compound

HRID 2397180Notes

Reaction equation

HRID 2397180 reaction equation
[CH2:1]([NH:4][CH2:5][CH:6]=[CH2:7])[CH:2]=[CH2:3].[CH2:8]([S:12](Cl)(=[O:14])=[O:13])[CH:9]([CH3:11])[CH3:10]>C1C=CC=CC=1>[CH2:1]([N:4]([CH2:5][CH:6]=[CH2:7])[S:12]([CH2:8][CH:9]([CH3:11])[CH3:10])(=[O:14])=[O:13])[CH:2]=[CH2:3]

Participants

4

Reactant 2

HCID 31279DiallylamineHCID 1822361-Propanesulfonyl chloride, 2-methyl-

Product 1

HCID 20324729HCID 20324729, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

A solution was formed containing 19.4 g. of diallylamine in 100 ml. of benzene. Then, 15.7 g. of isobutylsulfonyl chloride was added at such a rate that the temperature did not exceed 45° C. The mixture was stirred and refluxed for ten minutes, cooled, washed with 100 ml. of dilute hydrochloric acid and then with H2O. It was then dried over magnesium sulfate, filtered and evaporated to give 20.1 g. (02% of theory) of the product, a liquid, nD30 = 1.4697.

Workup

  1. customA solution was formed
  2. additioncontaining 19.4 g
  3. customdid not exceed 45° C
  4. temperaturerefluxed for ten minutes
  5. temperaturecooled
  6. washwashed with 100 ml
  7. dry with materialIt was then dried over magnesium sulfate
  8. filtrationfiltered
  9. customevaporated
  10. customto give 20.1 g

Sources & evidence

ORD record
ord-d1df65a0e6ed4291866cbde8772fa739
Source dataset
uspto-grants-1977_05
Patent number
US04021229

Reaction notes

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