HuagongsheHuagongshe Chemistry Print Report · For research reference only
Propionic Acid → 3,7-Dimethylocta-2,6-Dienal
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Propionic Acid | HCID 1032 | — |
| Reactant | 3-Methyl-2-buten-1-OL | HCID 11173 | — |
| Reactant | 3-Methyl-2-butenal | HCID 61020 | — |
| Solvent | Water | HCID 962 | — |
| Product | 3,7-Dimethylocta-2,6-Dienal | HCID 8843 | 51% |
Reaction Conditions
| Temperature | 130 °C |
|---|
Reaction Steps
A mixture of 100 parts of 3,3-dimethylacrolein, 200 parts of prenol and 150 parts of propionic acid is heated for three hours at 130° C., the water formed being distilled out azeotropically. The reaction product is worked up. 24 parts of citral is obtained. This is equivalent to yield of 51% of theory at a conversion of 26% (based on 3,3-dimethylacrolein).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04021411 |
| Source dataset | uspto-grants-1977_05 |
| ORD ID | ord-b781db8e381a4ddeb7356b3389df79e6 |
| Source note | uspto-grants-1977_05 |