Carbon Dioxide → Potassium 3,7,11-trimethyldodeca-2,4-dienoate

HRID 2397294Notes

Reaction equation

HRID 2397294 reaction equation
[CH3:1][C:2](/[CH:7]=[CH:8]\[CH2:9][CH:10]([CH3:17])[CH2:11][CH2:12][CH2:13][CH:14]([CH3:16])[CH3:15])=[CH:3][C:4]([OH:6])=[O:5].C(=O)(O)[O-].[K+:22].C(=O)=O>C1C=CC=CC=1>[CH3:1][C:2]([CH:7]=[CH:8][CH2:9][CH:10]([CH3:17])[CH2:11][CH2:12][CH2:13][CH:14]([CH3:16])[CH3:15])=[CH:3][C:4]([O-:6])=[O:5].[K+:22]

Participants

5

Reactant 3

HCID 280Carbon DioxideHCID 516893Potassium BicarbonateHCID 86734009cis 3,7,11-Trimethyldodeca-2,4-dienoic acid

Product 1

HCID 74083878Potassium 3,7,11-trimethyldodeca-2,4-dienoate

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

To a solution of 0.5 g. of trans/cis 3,7,11-trimethyldodeca-2,4-dienoic acid in 15 ml. of benzene is added with stirring an equivalent amount of potassium bicarbonate. The mixture is stirred until the evolution of carbon dioxide ceases and then evaporated to yield potassium 3,7,11-trimethyldodeca-2,4-dienoate.

Workup

  1. customevaporated

Sources & evidence

ORD record
ord-e54ced8652ff44fdb5d47361f881e6ad
Source dataset
uspto-grants-1977_05
Patent number
US04021461

Reaction notes

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