Vanadium trichloride oxide → HCID 178419405, compound

HRID 2397669Notes

Reaction equation

HRID 2397669 reaction equation
[O:1]=[V:2].Cl.Cl.Cl.BrC1C=CC([Si:13]([C:22]2[CH:27]=[CH:26][C:25]([Br:28])=[CH:24][CH:23]=2)(C2C=CC(Br)=CC=2)[OH:14])=CC=1>>[O-2:14].[Br:28][C:25]1[CH:26]=[CH:27][C:22]([SiH2:13][O:1][V+2:2]([O:14][SiH2:13][C:22]2[CH:23]=[CH:24][C:25]([Br:28])=[CH:26][CH:27]=2)[O:14][SiH2:13][C:22]2[CH:27]=[CH:26][C:25]([Br:28])=[CH:24][CH:23]=2)=[CH:23][CH:24]=1

Participants

3

Reactant 2

HCID 24410Vanadium trichloride oxideHCID 21494694Tris(4-bromophenyl)silanol

Product 1

HCID 178419405HCID 178419405, compound

Procedure

vanadium oxytrichloride was reacted with tri (p-bromophenyl) silanol, (m.p. = 120-121° C.) to produce tris[(p-bromophenyl)-siloxy]-vanadium oxide (m.p. = 175° C.); and

Sources & evidence

ORD record
ord-53d93dc99317451fbe51a8969fb9f4de
Source dataset
uspto-grants-1977_05
Patent number
US04022807

Reaction notes

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