HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Benzylidenebutanoic acid → 2-Benzylbutanoic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Benzylidenebutanoic acid | HCID 235117 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Sodium Hydroxide | HCID 14798 | — |
| Product | 2-Benzylbutanoic acid | HCID 21881 | 100% |
Reaction Steps
A solution of 35.2 gm (0.2 mol) of α-ethyl cinnamic acid in 450 ml of 3% sodium hydroxide was reduced in a hydrogen atmosphere at 60 psi using 4 gm of 5% palladium on charcoal. After hydrogen uptake had ceased, the reaction mixture was filtered, acidified with hydrochloric acid and extracted with ether. Evaporation gave 36 gm (0.2 mol) of 2-benzyl butanoic acid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04022814 |
| Source dataset | uspto-grants-1977_05 |
| ORD ID | ord-bae2a6957965486d905a0c1e072beae2 |
| Source note | uspto-grants-1977_05 |