HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,3,5-Triiodobenzoic acid → (3,5-Diiodophenyl)methanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,3,5-Triiodobenzoic acid | HCID 6948 | — |
| Reactant | Aluminium lithium hydride | HCID 21226445 | — |
| Product | (3,5-Diiodophenyl)methanol | HCID 12330868 | — |
Reaction Steps
Using the procedure of B. Gaux and D. LeHenaff, Bull. Soc. Chim. Fr. 34, 505 (1974), 2,3,5-triiodobenzoic acid (Aldrich) was treated with lithium aluminum hydride to give 3,5-diiodobenzyl alcohol mp 136.5°-140° (lit 137°). Using the procedure outlined in Example 4, 3,5-diiodobenzyl alcohol was treated with n-hexyl chloroformate giving s (ND25 = 1.5800).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04022814 |
| Source dataset | uspto-grants-1977_05 |
| ORD ID | ord-137f881abc9241f3b6a0591fc8e866b8 |
| Source note | uspto-grants-1977_05 |