1,6-Hexanediamine, N,N'-bis(2-methylpropyl)- → N,N'-(1,6-hexylene)-bis[N-isobutyl 2-hydroxyundecylamine]

HRID 2397812Notes

Reaction equation

HRID 2397812 reaction equation
[CH2:1]1[O:12][CH:2]1[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[CH2:13]([NH:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][NH:24][CH2:25][CH:26]([CH3:28])[CH3:27])[CH:14]([CH3:16])[CH3:15]>>[CH2:18]([N:17]([CH2:1][CH:2]([OH:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:13][CH:14]([CH3:15])[CH3:16])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][N:24]([CH2:1][CH:2]([OH:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:25][CH:26]([CH3:28])[CH3:27]

Participants

3

Reactant 2

HCID 1777221,6-Hexanediamine, N,N'-bis(2-methylpropyl)-HCID 5377372-Nonyloxirane

Product 1

HCID 21332453N,N'-(1,6-hexylene)-bis[N-isobutyl 2-hydroxyundecylamine]

Procedure

Condensation of 1-undecene oxide and N,N'-di(isobutyl)hexamethylenediamine affords N,N'-(1,6-hexylene)-bis[N-isobutyl-2-hydroxyundecylamine] (I: R= CH3 (CH2)8, R' = (CH3)2CHCH2, X= (CH2)6, Z= H).

Sources & evidence

ORD record
ord-d28c9c0d9d1d4f0d811e807511b0982d
Source dataset
uspto-grants-1977_05
Patent number
US04022833

Reaction notes

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