Ethylenediamine → N,N'-ethylenebis[2-hydroxyundecylamine]

HRID 2397816Notes

Reaction equation

HRID 2397816 reaction equation
[CH2:1]1[O:12][CH:2]1[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[CH2:13]([NH2:16])[CH2:14][NH2:15]>C(O)C>[CH2:13]([NH:16][CH2:1][CH:2]([OH:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:14][NH:15][CH2:1][CH:2]([OH:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]

Participants

4

Reactant 2

HCID 3301EthylenediamineHCID 5377372-Nonyloxirane

Product 1

HCID 21332391N,N'-ethylenebis[2-hydroxyundecylamine]

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

In a manner similar to that of Example 1, condensation of 1-undecene oxide (40 g.) and ethylenediamine (7.07 g.) and two recrystallizations of the resulting solid (14.9 g.) from ethanol gave N,N'-ethylenebis[2-hydroxyundecylamine] (I: R= CH3 (CH2)8, R' = H, X= (CH2)2, Z= H) (12.4 g., m.p. 130.2°-137.8° C.).

Sources & evidence

ORD record
ord-b8d31c22314a49e994796c8adc782911
Source dataset
uspto-grants-1977_05
Patent number
US04022833

Reaction notes

Loading…