HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methane → HCID 21390710, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methane | HCID 297 | — |
| Reactant | 4-Nitrobenzoyl chloride | HCID 8502 | — |
| Reactant | 50892-99-4 | HCID 3039624 | — |
| Solvent | Boron trifluoride etherate | HCID 8000 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | HCID 21390710 | HCID 21390710 | 75% |
Reaction Steps
To a solution of 2-furanamidoxime (12.6 g, 0.1 mole) and p-nitrobenzoyl chloride (18.1 g, 0.1 mole) in 500 ml of dry dioxane, 1 ml of BF3 -ethyl ether is added and the mixture is heated to reflux for 16 hours. Evaporation of the solvent in vacuo gives a light brown solid. It is decolorized with Darco (CHCl3) and crystallized from ethanol-acetonitrile to give 19.2 g (75%) of product, m.p. 168°-170° .
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04022901 |
| Source dataset | uspto-grants-1977_05 |
| ORD ID | ord-5399df89cf8a4505847e6aa567d92a01 |
| Source note | uspto-grants-1977_05 |