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HRID2397896

反应详情

EQUATION

反应方程式

HRID 2397896 的结构方程式

REACTANTS

反应物

3
结构：O=C1CCCC(=O)C1
HCID10434

1,3-Cyclohexanedione

C6H8O2

结构：COc1cc(C=O)c([N+](=O)[O-])cc1OC
HCID88505

6-Nitroveratraldehyde

C9H9NO5

结构：CCOC(=O)CC(=N)N
HCID4599837

Carbamimidoyl-acetic acid ethyl ester

C5H10N2O2

PRODUCTS

生成物

1
结构：CCOC(=O)C1=C(N)NC2=C(C(=O)CCC2)C1c1cc(OC)c(OC)cc1[N+](=O)[O-]
HCID70635419

未命名化合物

收率 52%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCO
溶剂HCID702

Ethanol

C2H6O

2 次

PROCEDURE

实验过程

Boiling a solution of 8.5 g of 6-nitroveratraldehyde, 4.0 g of cyclohexane-1,3-dione and 5.2 g of amidinoacetic acid ethyl ester in 150 ml of ethanol for 1 hour yields 2-amino-4 -(2-nitro-4,5-dimethoxyphenyl)-1,4,5,6,7,8-hexahydro-5-oxoquinoline- 3-carboxylic acid ethyl ester of melting point 261° C. (ethanol).

WORKUP

后处理

  1. customfor 1 hour