HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,3-Cyclohexanedione → HCID 86733067, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,3-Cyclohexanedione | HCID 10434 | — |
| Reactant | Carbamimidoyl-acetic acid ethyl ester | HCID 4599837 | — |
| Reactant | 2-azidobenzaldehyde | HCID 10888060 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 86733067 | HCID 86733067 | 58% |
Reaction Steps
Upon heating a solution of 7.4 of 2-azidobenzaldehyde, 5.6 g of cyclohexane-1,3-dione and 6.5 g of amidinoacetic acid ethyl ester in 100 ml of ethanol for 4 hours, 2-amino-4-(2-azidophenyl)-1,4,5,6,7,8-hexahydro-5-oxoquinoline-3-carboxylic acid ethyl ester of melting point 209° C. (ethanol) is obtained. Yield: 58% of theory.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04022898 |
| Source dataset | uspto-grants-1977_05 |
| ORD ID | ord-cceda3edf4b84fff8e62171d7251a7d6 |
| Source note | uspto-grants-1977_05 |