4-Androstene-17beta,19-diol → 4-Androstene-17beta,19-diol dipropionate
Reaction equation
C[C@]12CC[C@H]3[C@@H](CCC4[C@]3(CO)CCCC=4)[C@@H]1CC[C@@H]2O.[C:22]([O:26][C@H:27]1[CH2:32][CH2:31][C@H:30]2[C@H:33]3[C@H:48]([CH2:49][CH2:50][C@:28]12[CH3:29])[C@:41]1([CH2:42][O:43][C:44](=[O:47])[CH2:45][CH3:46])[C:36](=[CH:37][CH2:38][CH2:39][C@@H:40]1C)[CH2:35][CH2:34]3)(=[O:25])[CH2:23][CH3:24]>>[C:22]([O:26][C@H:27]1[CH2:32][CH2:31][C@H:30]2[C@H:33]3[C@H:48]([CH2:49][CH2:50][C@:28]12[CH3:29])[C@:41]1([CH2:42][O:43][C:44](=[O:47])[CH2:45][CH3:46])[C:36](=[CH:37][CH2:38][CH2:39][CH2:40]1)[CH2:35][CH2:34]3)(=[O:25])[CH2:23][CH3:24]Participants
3
Procedure
Substituting 4-androstene-17β,19-diol for the 1α-methyl-4-androstene-17β,19-diol above results in the formation of 4-androstene-17β,19-diol dipropionate.
Sources & evidence
- ORD record
- ord-cf20d5710bc74087ab152432c4834043
- Source dataset
- uspto-grants-1977_05
- Patent number
- US04022769
Reaction notes
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