Sodium Hydroxide → HCID 131710746, compound

HRID 2398012Notes

Reaction equation

HRID 2398012 reaction equation
[OH-:1].[Na+:2].[CH2:3]1[N:8]2[CH2:9][N+:10]3([CH2:13]/[CH:14]=[CH:15]\[Cl:16])[CH2:12][N:6]([CH2:7]2)[CH2:5][N:4]1[CH2:11]3.[Cl-:17]>O>[CH2:5]1[N:4]2[CH2:11][N+:10]3([CH2:13]/[CH:14]=[CH:15]\[Cl:16])[CH2:9][N:8]([CH2:3]2)[CH2:7][N:6]1[CH2:12]3.[Cl-:17].[OH-:1].[Na+:2]

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 6435993Chloroallyl methenamine chloride

Product 1

HCID 131710746HCID 131710746, compoundYield 78%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Excess sodium hydroxide, preferably, 4 molar proportions, is dissolved in water and cooled to room temperature. A quantity of about one mole of Dowicil 200 antimicrobial is added slowly to the caustic solution and the reaction mixture is stirred approximately 15 minutes at ambient temperature. The ⟦Carbinolamine⟧ basic oil which forms is extracted with benzene, the extract is dried over sodium sulfate and the benzene is evaporated to give the ⟦Carbinolamine⟧ basic oil in an approximately 78% yield as a viscous oil.

Workup

  1. extractionThe ⟦Carbinolamine⟧ basic oil which forms is extracted with benzene
  2. dry with materialthe extract is dried over sodium sulfate
  3. customthe benzene is evaporated
  4. customto give the ⟦Carbinolamine⟧ basic oil in an approximately 78% yield as a viscous oil

Sources & evidence

ORD record
ord-b054eaaa1f744db2bd0e7afea90833ee
Source dataset
uspto-grants-1977_05
Patent number
USRE029225

Reaction notes

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